An NMR and molecular dynamics investigation of the avian prion hexarepeat conformational features in solution

Adriana Pietropaolo,Luca Raiola,Luca Muccioli,Giustiniano Tiberio,Claudio Zannoni,Roberto Fattorusso,Carla Isernia,Diego La Mendola,Giuseppe Pappalardo,Enrico Rizzarelli

Chemical Physics Letters（2007）

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摘要

The effect of proline cis–trans isomerisation on the conformational behaviour of avian prion hexarepeat Ac-PHNPGY-NH2 is investigated at acid, neutral and basic pH [a,b,c], revealing a shift from turn-like structures to unordered ones.

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