The syntheses, structures and redox properties of phosphine-gold(I) and triruthenium-carbonyl cluster derivatives of tolans

Wan M. Khairul,David Albesa-Jové,Dmitri S. Yufit, Maha R. Al-Haddad, Jonathon C. Collings,František Hartl,Judith A.K. Howard,Todd B. Marder,Paul J. Low

Inorganica Chimica Acta（2008）

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摘要

Crystallographic, spectroscopic, electrochemical and IR spectroelectrochemical methods have been used to study the complexes [Ru3(μ-AuPPh3)(μ-η1,η2-C2C6H4CCC6H4X)(CO)7(μ-dppm)] and related mononuclear gold species, revealing little interaction between the remote substituent and the cluster core.

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关键词

Tolan,Ruthenium cluster,Gold complex,Electrochemistry,Spectroelectrochemistry

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