Visualisation of axial chirality using 2H-{1H} NMR in poly(γ-benzyl L-glutamate),a chiral liquid crystal solvent

William Smadja,Sandie Auffret,Philippe Berdagué,Denis Merlet,Cécile Canlet,Jacques Courtieu,Philippe Berdagué,Jean-Yves Legros,André Boutros,Jean-Claude Fiaud

CHEMICAL COMMUNICATIONS（1997）

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摘要

Disubstituted, racemic, axially chiral compounds with true and isotopic chiralities have been discriminated through the differential ordering effect of enantiomers when dissolved in a chiral liquid crystal solvent made of organic solutions of poly(gamma-benzyl L-glutamate).

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