Synthesis Of N-Confused Phlorins Via An Addition/Cyclization Pathway

Xiaofang Li,Piotr J Chmielewski,Junfeng Xiang,Jialiang Xu,Li Jiang,Yuliang Li,Huibiao Liu,Daoben Zhu

JOURNAL OF ORGANIC CHEMISTRY（2006）

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摘要

The syntheses of N-confused phlorins are provided by reactions of N-confused porphyrins with nitrilimines and with dialkyl acetylenedicarboxylate. Both reactions involve zwitterionic intermediates and proceed through an addition/cyclization pathway.

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