Cu(I) and Ag(I) complexes of chalcogenide derivatives of the organometallic ligand dppf and the dppa analogue

Huizhang Liu,Nuno A.G. Bandeira,Maria José Calhorda,Michael G.B. Drew,Vitor Félix,Josef Novosad,Fabrizia Fabrizi de Biani,Piero Zanello

Journal of Organometallic Chemistry（2004）

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摘要

Short Se⋯Se contacts in the solid state are observed between adjacent [Cu4{Ph2P(Se)NP(Se)Ph2}3]+ clusters units, but not for the S analogue. They correspond to weak bonds according to DFT calculations performed on suitable models.

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关键词

Cu(I) complexes,Ag(I) complexes,Crystal structures,Clusters,DFT calculations,Electrochemistry

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