Transparent conductive characteristics of Ti:ITO films deposited by RF magnetron sputtering at low substrate temperature
Surface and Coatings Technology(2010)
摘要
Transparent conductive metal oxide films of titanium-doped indium–tin-oxide (Ti:ITO) and indium-tin-oxide (ITO) were deposited by a dual target type radio frequency (RF) magnetron sputtering, and the films were applied to dye-sensitized solar cells (DSCs). Electrical and optical properties of the films were investigated as well as the film structure and morphology. At an annealing temperature of 450°C, the resistivity of the Ti:ITO and ITO films are about 5×104 and 1.1×103Ωcm, and the transmittances of both films at a wavelength of 550nm reach about 85–90%. The impedance in the Ti:ITO-based DSC sample is 31.9, 49.6, and 20.2, for the counter electrode, the TiO2/dye/electrolyte interface, and the carrier transport by ions within the electrolyte, respectively. The series resistance, Rs, is about 72.4Ω. Photoconversion efficiency (η) in the Ti:ITO-based DSC sample is 3.75% (ff: 0.54, Voc: 0.71V, Jsc: 9.82mA/cm2) at 100mW/cm2 light intensity.
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关键词
Transparent conductive oxide,Ti:ITO film,Dye-sensitized solar cell,RF magnetron sputtering
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