A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Belén Galán,Marta E. G. Mosquera,Julie S. Palmer,Paul R. Raithby,Dominic S. Wright

Journal of the Chemical Society, Dalton Transactions（1999）

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摘要

Controlled hydrolysis of the cubane [SnNtBu]4 with H2O int thf-MeCN provides a direct route to the oxo complex [Sn4(NtBu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4(NtBu)3(Nnaph)] at the sole product.

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关键词

selective functionalisation,snii

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