Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, andN-Hydroxy Carbamates

Cara Cesario,Lawrence P. Tardibono,Marvin J. Miller

JOURNAL OF ORGANIC CHEMISTRY（2009）

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摘要

Titanocene(III) chloride (Cp2TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72-95%). Reactions may be performed with stoichiometric Cp2TiCl or with catalytic Cp2TiCl.

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