ChemInform Abstract: Toluene-p-sulfonyl-mediated Radical Cyclization of Bis(allenes) Utilizing p-TsBr and p-TsSePh.

Suk‐Ku Kang,Young‐Hwan Ha,Doo‐Hwan Kim,Yoongho Lim, Ju Yeon Jung

ChemInform（2010）

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摘要

The regio- and stereoselective toluene-p-sulfonyl-mediated radical cyclization of bis(allenes) with p-TsBr and p-TsSePh was carried out in the presence of a catalytic amount of AIBN to afford the trans-fused five-membered ring containing vinyl sulfones and bromide or selenide functionalities.

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radical cyclization,cheminform abstract,bisallenes,bisallenes,toluene-p-sulfonyl-mediated,p-tsbr,p-tsseph

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