Magneto-structural study on a tetracopper(II) Schiff base complex stabilizing a decanuclear water aggregate

Sunil G. Naik,Arindam Mukherjee,Rajamani Raghunathan,Munirathinam Nethaji,Suryanarayanasastry Ramasesha,Akhil R. Chakravarty

Polyhedron（2006）

引用 11|浏览4

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摘要

An antiferromagnetically spin-coupled tetranuclear copper(II) Schiff base complex [Cu4L2(3-ppz)2] (1) containing the 3-phenylpyrazole ligand has been prepared and structurally characterized. The crystal structure of 1·6H2O shows the formation of a decameric water cluster having two dimeric and one cyclic chair hexameric water aggregate anchored onto two complex units through hydrogen bonding interactions.

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关键词

Tetracopper(II) complex,Crystal structure,Magnetic properties,Decameric water aggregate,Supramolecular assembly,Schiff base

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