ChemInform Abstract: New and Facile Synthesis of 5,6,7,8-Tetrahydro-5-deaza-5-thiapterins via the Aliphatic S-N Type Smiles Rearrangement.

Cheminform（2010）

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摘要

5,6,7,8-Tetrahydro-5-deaza-5-thiapterins (1a, 1d, and 1e), were conveniently synthesized by the thermal condensation of 5-bromo-6-chloroisocytosine (5) with cysteamines (6a-c) via the aliphatic S-N type Smiles rearrangement in ethanolic pH 7.0 buffer solution.

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关键词

5,6,7,8-TETRAHYDRO-5-DEAZA-5-THIAPTERIN,SYNTHESIS,THERMAL CONDENSATION,5-BROMO-6-CHLOROISOCYTOSINE,CYSTEAMINE,SMILES REARRANGEMENT

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