Synthesis of the sex pheromone of the obscure mealybug, the first example of a new class of monoterpenoids

Tetrahedron Letters（2007）

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摘要

The title compound was synthesized using a PPA-catalyzed cyclization, and diastereoselective quenching of a key intermediate to set up the relative stereochemistry of the methyl groups.

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关键词

1-Acetoxymethyl-2,3,4,4-tetramethylcyclopentane,Pheromone,Irregular terpenoid,Acid-catalyzed cyclization,Stereoselective enolate quench

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