Synthesis of highly pure oxyphytosterols and (oxy)phytosterol esters

Philippe Geoffroy,Diane Julien-David,Eric Marchioni,Francis Raul,Dalal Aoudé-Werner,Michel Miesch

Steroids（2008）

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摘要

The synthesis of several oxyphytosterols is described starting from stigmasterol, the key step being the regioselective hydrogenation of the 22–23 double bond of the latter.

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关键词

Hydrogenation,Nickel-Raney catalyst,Regioselectivity,Epoxydes,Bromohydrins

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