A metallated primary arsine; synthesis and structure of [PhAsHLi·2thf ]∞

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS(1999)

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摘要
The lithium primary arsenide [PhAsHli . 2thf](infinity), obtained by reaction of (BuLi)-Bu-n with PhAsH2 in toluene-thf, crystallises in the form of helical polymers; the structure of the right-hand enantiomorph has been obtained.
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