ChemInform Abstract: Intramolecular Organolithium Addition to Indol-2(3H)-ones; an Approach to the Synthesis of Pyrrolo[1,2-a]indoles and Pyrido[1,2-a]indoles.

Cheminform（2010）

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摘要

Cyclisation of 3 and 10 by lithium–halogen exchange followed by reduction with lithium aluminium hydride gives pyrrolo[1,2-a]indoles 11 and 13 respectively. Similar treatment of bromides 4a and 4b gives pyrido[1,2-a]indoles 12a and 12b.

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intramolecular organolithium addition,synthesis,cheminform abstract

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