Reaction of (E)-phenyl 2-pyridyl ketone O-acyloximes (PPAO) with Grignard reagents. A convenient and highly chemoselective synthesis of ketones.

Tadayo Miyasaka,Hideaki Monobe,Shunsaku Noguchi

CHEMISTRY LETTERS（1986）

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摘要

The reaction of (E)-phenyl 2-pyridyl ketone O-acyloximes (PPAO) with Grignard reagents was found to be widely applicable to the chemoselective synthesis of various ketones in good yields under mild conditions.

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