Evidence for Ionic Interaction between Cationic Surfactant and Anionic Intermediate Generated in Cathodic Reduction of Acetophenone.

Yorimitsu Kodama,Akihito Fujiwara,Hideki Kawamoto,Nobuaki Ohta,Akira Kitani,Sotaro Ito

CHEMISTRY LETTERS（2001）

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摘要

The cathodic reduction of acetophenone in the presence of a chiral cationic surfactant in aqueous media gave S- or R-1-phenylethanol with 8-12 % ee. The observed enantioselectivity clearly suggests the interaction between the cationic surfactants and the anionic intermediate generated from the one-electron reduction of acetophenone.

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