New 2-aminoethylimidazole-based dicarboxylic acid receptor derived from cholestane

Tetrahedron Letters(2010)

引用 17|浏览4
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摘要
A new facial amphiphile cholestane-based receptor 1 containing 2-imidazolylethylamino moiety at the 3α and 7α positions of cholestane was synthesized. Recognition selectivity of the new receptor 1 with various dicarboxylic acids was assessed by 1H NMR titration. Maleic acid showed the highest binding constant among all the tested acids (Ka=9.36×104M−1).
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关键词
Molecular recognition,Dicarboxylic acid,Maleic acid,2-Aminoethylimidazole,Cholestane
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