Kinetics And Mechanisms Of The Permanganate Oxidation Of L-Valine In Neutral Aqueous-Solutions
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS(1989)
摘要
The permanganate oxidation of L-valine has been studied by visible spectrophotometry in neutral aqueous solutions. Under these conditions, both the zwitterionic and anionic forms of the amino acid are oxidized, the reaction being autocatalyzed by soluble colloidal manganese dioxide. Kinetic data for both the uncatalyzed and autocatalytic reaction pathways have been obtained, and reaction sequences consistent with the experimental findings are proposed.
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关键词
kinetics,chemical,aqueous solution
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