Investigation Of The Stereospecificity Of Clavaminic Acid Synthase In The Desaturation Of Dihydroclavaminic Acid To Clavaminic Acid

Je Baldwin,Rm Adlington,Np Crouch, Dj Drake, Y Fujishima, Sw Elson,Kh Baggaley

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS（1994）

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摘要

Incubations of (4R)- and (4S)-[4-H-2(1)]-proclavaminic acid with clavaminic acid synthase resulted in the stereospecific removal of the deuterium and hydrogen respectively from C-4, in their conversions to clavaminic acid, suggesting an enzyme catalysed syn-elimination for the desaturation of dihydroclavaminic acid to clavaminic acid.

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关键词

clavaminic acid synthase,clavaminic acid,dihydroclavaminic acid

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