Unexpected difference in enantioselective retention on cellulase (CBH I) silica stationary phase caused by exchange of potassium for sodium ion in the mobile

M Hedeland, S Jonsson, R Isaksson, C Pettersson

Chirality（1998）

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摘要

An increase in both retention and enantioselectivity for some p-blocking agents was observed when exchanging potassium to sodium ion in the buffer used as mobile phase. A large effect of ionic strength on retention was observed, while the enantioselectivity was constant. Chirality 10:513-518, 1998. (C) 1998 Wiley-Liss, Inc.

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关键词

CBH I,cellulase,cation,sodium,potassium,enantioselectivity and temperature,ionic strength

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