Diastereoselective Synthesis Of A Spironoraristeromycin Using An Acylnitroso Diels-Alder Reaction

Weimin Lin,Kristopher G. Virga,Kyung-Hee Kim,Jaroslav Zajicek,David Mendel,Marvin J. Miller

JOURNAL OF ORGANIC CHEMISTRY（2009）

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摘要

The tert-butyl N-hydroxycarbamate-derived nitroso reagent I reacted with N-Cbz-protected spirocyclic diene 2 to provide spirocycloadduct 3. Here we describe the efficient conversion of 3 into the novel carbocyclic nucleoside spironoraristeromycin 4.

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organic chemistry

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