Pressure-induced line mixing in the ν4 band of NH3 perturbed by O2 and self-perturbed

Journal of Molecular Spectroscopy(2009)

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摘要
Pressure-induced line-mixing parameters of 231 rovibrational transitions of several branches in the ν4 band of ammonia perturbed by O2 have been measured at room temperature (295K) using a high-resolution Fourier transform spectrometer. The line-mixing parameters were obtained using the method of multi-spectrum fitting to the measured shapes of the lines, including the interference effects caused by the line overlaps.
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关键词
Line mixing,Self-mixing,Semiclassical model,State-to-state cross sections,Ammonia
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