Asymmetric synthesis of C-19 to C-27 fragment of rifamycin-S

TETRAHEDRON LETTERS(1995)

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摘要
A highly stereoselective asymmetric synthesis of C-19 to C-27 fragment of Rifamycin-S consisting of 7 contiguous asymmetric centres is described involving Ipc(2)BH as the chiral hydroborating reagent.
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asymmetric synthesis
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