Facile Synthesis of Ginsenoside Ro

Wenjie Peng,Jiansong Sun,Feng Lin,Xiuwen Han,Biao Yu

SYNLETT（2004）

引用 39|浏览9

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摘要

Two concise synthetic routes, being different in the glycosylation sequence, toward ginsenoside Ro (1) are developed. These syntheses feature the elaboration of the glucuronide residue at a later stage via the TEMPO-mediated selective oxidation and the installation of AZMB as a benzoylic neighboring participating group capable of being selectively removed afterward.

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关键词

ginsenoside Ro,triterpene saponin,synthesis,glycosylation,oxidation

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