Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water.

Fu-Xin Chen,Cheng Shao,Qian Liu,Pin Gong,Chun-Liang Liu,Rui Wang

CHIRALITY（2009）

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摘要

A mild method for the asymmetric synthesis of quaternary and tertiary carbon centers has been developed through Michael addition of trisubstituted carbon nucleophile to nitroalkenes catalyzed by low loading sodium demethylquinine salt in water. Chirality 21:600-603, 2009. (C) 2008 Wiley-Liss, Inc.

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关键词

organocatalysis,nitroalkenes,quinine derivate,quaternary carbon centers,water

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