Rhodium catalysed carbonylation of homoallylic alcohols to spiropyrans bearing quaternary centres

TETRAHEDRON(1998)

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摘要
A convenient preparation of substituted spiropyrans via rhodium catalysed hydroformylation of homoallylic alcohols, followed by a condensation sequence to form hemiacetals and 2,2,3,3 -tetraalkyl-4[H] -pyrans, is described. (C) 1998 Elsevier Science Ltd. All rights reserved.
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关键词
alcohols,pyrans,rhodium catalysis,spiro compounds
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