A Convenient Preparation Of 1,2,3,4,5,6,7,8-Octahydro-Naphthalene Skeleton. Synthesis Of (+/-)-Isocaridiene

Paulo M Imamura,Marta Costa,Rog�rio Cust�dio

SYNTHETIC COMMUNICATIONS（2006）

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摘要

Synthesis of isocaridiene, an isomeric compound of natural sesquiterpene caridiene, is described starting from myrcene. Dehydration of tertiary alcohol leading exclusively to isocaridiene was in agreement with the semiempirical and ab initio quantum mechanical calculations.

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terpenes

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