Capillary electrophoretic separation of herbicidal enantiomers applying ergot alkaloids

The capillary electrophoretic separation of some herbicidal enantiomers is shown applying 1-allylterguride as chiral selector. Baseline separation is shown for the enantiomers of fluazifop, halossifop and fenoxaprop, whereas the optical isomers of flamprop could be partially resolved. Separation times are short compared to similar analyses, applying HPLC and a terguride chiral stationary phase. The degree of dissociation of the acidic analytes, as well as the amount of methanol present in the background electrolyte, are shown to have a major influence on enantioresolution, as expected form earlier studies.