Convenient synthesis of heteroaryl-linked benzimidazoles via microwave-assisted boronate ester formation

Tara R. Rheault,Kelly H. Donaldson,Mui Cheung

Tetrahedron Letters（2009）

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摘要

N-Substituted 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzimidazoles were conveniently accessed via microwave-assisted synthesis. Subsequent Suzuki–Miyaura reaction with heteroaryl halides proceeded to give a wide variety of 5-heteroaryl-substituted benzimidazoles.

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