Studies Of A Poly(Phenylenevinylene) Without C-2h Symmetry
SYNTHETIC METALS(2001)
摘要
We have investigated the photophysics of the luminescent polymer poly(1,3-phenylenevinylene-alt-2,5-dioctyloxy-1,4-phenylenevinylene) (1,3-PPV) by a variety of optical spectroscopies. The incorporation of alternating metaphenylene and para-phenylene rings reduces the conjugation length with respect to poly(para-phenylene vinylene) derivatives. As a consequence, excited states are blue-shifted and the nonlinear susceptibility is reduced. The reduced symmetry of 1,3-PPV modifies optical selection rules, resulting in strong overlap of the fluorescence spectrum with excited state absorption by charged polarons.
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关键词
PPV, symmetry, photophysics, polarons
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