A reversible metal-ligand bond break associated to a spin-crossover.

Chemical Communications(2007)

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摘要
The [Fe(II)L(CN)(2)].H(2)O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.
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关键词
metal–ligand bond break,reversible metal–ligand,spin-crossover
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