An enantioselective Michael addition of malonate to nitroalkenes catalyzed by low loading demethylquinine salts in water

Fu-Xin Chen,Cheng Shao,Quan Wang,Pin Gong,Dong-Yan Zhang,Bang-Zhi Zhang,Rui Wang

Tetrahedron Letters（2007）

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摘要

An enantioselective Michael addition of malonate to nitroalkenes is efficiently catalyzed by low loading demethylquinine salts in water; the yield range from 49% to 93% and the ee up to 90%.

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关键词

Organocatalysis,Michael addition,Salt catalysis,Nitroalkenes,Water

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