An Efficient Procedure Based On A Mw-Assisted Horner-Wadsworth-Emmons Reaction For The Synthesis Of (Z)-3,3-Trisubstituted-Alpha,Beta-Unsaturated Esters

Daniela Rossi,Anna Carnevale Baraglia,Massimo Serra,Ornella Azzolina,Simona Collina

MOLECULES（2010）

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摘要

A microwave-assisted HWE olefination process of readily accessible aryl-alkyl ketones has been developed to provide a rapid access to (Z)-3,3-trisubstituted- alpha,beta-unsaturated methyl esters, key building blocks for the synthesis of biologically active compounds.

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关键词

(Z)-3,3-trisubstituted alpha,beta-unsaturated methyl esters, aryl-alkyl ketones, Horner-Wadsworth-Emmons reaction, microwave-assisted reactions

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