Electron-transfer substitution reactions: Facilitation by the cyano group11Paper 34 in the series “Substitution Reactions Which Proceed via Radical Anion Intermediates.” For preceding paper, see Kornblum, N.; Chen, S.I.; Kelly, W.J. J. Orp. Chem.1988, 53, 1830. This paper derives from the Ph.D. thesis of M.J. Fifolt, Purdue University, December 1977

TETRAHEDRON, pp. 1311-1322, 1989.

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It is now clear that a cyane group facilitate electron-transfer substitution reactions. of particular interest is the demonstration that electron-transfer chain substitution at a staturated carbon atom has been achieved in the absence of a nitro group.



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