One-pot synthesis of 2-aminobenzimidazoles using 2-chloro-1,3-dimethylimidazolinium chloride (DMC)

Gerald D. Artman,Catherine F. Solovay,Christopher M. Adams,Brian Diaz,Martin Dimitroff,Takeru Ehara,Danlin Gu,Fupeng Ma,Donglei Liu,Bridget R. Miller,Teresa E. Pick,Daniel J. Poon,David Ryckman,David A. Siesel,Brady S. Stillwell,Tyson Swiftney,Jonathan P. van Dyck,Chun Zhang,Nan Ji

Tetrahedron Letters（2010）

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摘要

2-Chloro-1,3-dimethylimidazolinium chloride (DMC or DMC-Cl) has been found to effectively and rapidly generate 2-aminobenzimidazoles from 1,2-diaminoarenes and isothiocyanates in moderate to good yields at room temperature in a one-pot operation.

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room temperature

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