On the Construction of Bicyclo [m.3.0] Bridged Alkenes: Thermal Rearrangement of Spirocyclic Vinylcyclopropanes

TETRAHEDRON LETTERS(1992)

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摘要
A facile transformation of spirocyclic vinylcyclopropanes to titled bridged-alkenes is presented; this approach finds an application in the synthesis of natural product carbon framework of diverse nature such as that of precapnelladiene and muscone.
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