An approach to erythronolide A seco acid via a simple tetronic acid

Richard H. Schlessinger,Adnan M. M. Mjalli,Alan D. Adams,James P. Springer,Karst Hoogsteen

JOURNAL OF ORGANIC CHEMISTRY（1992）

引用 29|浏览11

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摘要

The unsaturated aldehyde 1, a key intermediate in our approach to erythronolide A seco acid (2), has been prepared from the simple tetronic acid 6 by its seriatim transformations into the vinylogous urethanes 5, 9, and 11 concluding with reductive conversion of the latter into 1.

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