Tetrachlorotetrakis(propan-2-ol)uranium(IV) and tetrachlorotetrakis(propan-2-ol)thorium(IV)

P. L. Gordon,J. A. Thompson,J. G. Watkin,C. J. Burns,N. N. Sauer,B. L. Scott

Acta Crystallographica Section C-crystal Structure Communications（1999）

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摘要

The title complexes, [UCl4(C3H8O)(4)] and [ThCl4(C3H8O)(4)], are isomorphous and crystallize in the tetragonal space group I4(1)/a. The molecules have approximate dodecahedral symmetry and occupy sites of 4 symmetry. Principal bond lengths include U-Cl = 2.6478(10), U-O = 2.478(3), Th-Cl = 2.7066(8) and Th-O = 2.515 (2) Angstrom.

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