Tetrazole derivatives and matrices as novel cobalamin coordinating compounds
Journal of Organometallic Chemistry(2007)
摘要
We have found that tetrazole derivatives can coordinate to H2O·cobalamin. A specific group (presumably tetrazole) can be easily created in CNBr-activated Sepharose by treatment with azide. The prepared matrix contained ≈10mM of the active groups, which bound H2O·corrinoids with Kd=10−5–10−6M.
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关键词
ATZ,Bzm,Cbl,Ado·/Me·/H2O·/CN·Cbl,Cbi,GSH,His,Im,Pi,RTZ,STZ,TZ
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