Photocyclization of α,β-unsaturated amide aldehydes synthesis of jatropham

James P. Dittami,Feng Xu,Hua Qi,Matthew W. Martin,Jon Bordner,Debra L. Decosta,Jeffrey Kiplinger,Philip Reiche,Richard Ware

TETRAHEDRON LETTERS（1995）

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摘要

alpha,beta-unsaturated amide aldehydes undergo photoisomerization and intramolecular cyclization to provide hydroxy substituted pyrrolidinone systems. A synthesis of the natural product jatropham was accomplished by application of this procedure.

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