Catalytic polymerization of ε-caprolactone in air

Antti Pärssinen,Martin Kohlmayr,Markku Leskelä,Mohammed Lahcini,Timo Repo

POLYMER CHEMISTRY（2010）

引用 17|浏览10

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摘要

A highly efficient, catalytic open-air ring opening polymerization for cyclic esters is reported. Using titanium alkoxides, Ti(OiPr)(4) and Ti(OnBu)(4), as catalysts reproducible ROPs even with high monomer/initiator ratios without protecting gas are feasible.

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