(Amidomethyl)dimethylsilanol hydrohalides: Synthesis, NMR and IR studies. Characteristic features of the electronic structure from high-resolution X-ray study and quantum chemical calculation

Alexander A. Korlyukov,Sergey A. Pogozhikh,Yuri E. Ovchinnikov,Konstantin A. Lyssenko, Mikhail Yu. Antipin,Aleksander G. Shipov,Oksana A. Zamyshlyaeva,Evgeniya P. Kramarova,Vadim V. Negrebetsky,Igor P. Yakovlev,Yuri I. Baukov

Journal of Organometallic Chemistry（2006）

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摘要

(C,O)-chelate silanol hydrohalides RC(O)NHCH2SiMe2OH·HHal, their precursors, chlorides RC(O)NHCH2SiMe2Cl and disiloxanes [RC(O)NHCH2SiMe2]2O were obtained by several routes. The original scheme of hydrolysis of the above chlorides was discussed in detail. The electron structure of silanol hydrohalides have been investigated using high-resolution X-ray study and quantum chemical calculations.

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关键词

Pentacoordinated silicon compounds, synthesis,X-ray diffraction study, intramolecular coordination, intermolecular coordination,Quantum chemical calculations, distribution of electron density

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