Rate enhancement by water in a TiCl4-mediated stereoselective vinylogous Mukaiyama aldol reaction

Makoto Yamaoka,Atsuo Nakazaki,Susumu Kobayashi

Tetrahedron Letters（2010）

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摘要

A remarkable enhancement in the rate of a TiCl4-mediated stereoselective vinylogous Mukaiyama aldol reaction (VMAR) using vinylketene silyl N,O-acetal 1 was observed in the presence of water.

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关键词

Vinylogous Mukaiyama aldol reaction,Rate enhancement,Water,TiCl4-mediated reaction

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