ChemInform Abstract: Phosphadisilacyclobutenes by Stepwise Silylene Additions to Phosphaalkynes.

M. WEIDENBRUCH,S. OLTHOFF,K. PETERS,H. G. VON SCHNERING

Cheminform（2010）

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摘要

The phosphaalkynes RC = P [R = l-adamantyl (la) or R = 2-methylcyclohexyl (Ib)] react with dimesitylsilylene, presumably by [2+1] cycloaddition followed by silylene insertion, to furnish phosphadisilacyclobutenes; the molecular structure of the adamantyl derivative was determined by X-ray crystallography.

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