基本信息
浏览量:8
职业迁徙
个人简介
Currently the Mulvey group is developing the special synergistic chemistry that can be created through combining distinct components (mixtures of different metals and different ligands) within the same molecular environment. Fundamentally it could be said that mixing two distinct metal compounds, for example a lithium amide and a magnesium bisalkyl, produces a heterometallic molecule which acts neither as a lithium nor a magnesium compound but a compound of a unique new metallic element! Novel chemistry, beyond the scope of conventional homometallic reagents, is the reward. This idea has been applied to metallation chemistry. Metallation (transforming inert C-H bonds to reactive, useful C-Metal bonds) is one of the most important bond-making tools in chemistry, used routinely in synthetic laboratories worldwide, and increasingly employed from milligram to ton scales in fine chemical and pharmaceutical manufacture. In alkali-metal-mediated metallation the alkali metal is the catalyst while the formally less reactive metal (for example, magnesium or zinc) executes the deprotonation (low polarity metallation). Major challenges are to turn stoichiometric metallation reactions into catalytic processes and to invent ways of achieving unusual regioselectivities across a broad range of substrates.
研究兴趣
论文共 132 篇作者统计合作学者相似作者
按年份排序按引用量排序主题筛选期刊级别筛选合作者筛选合作机构筛选
时间
引用量
主题
期刊级别
合作者
合作机构
Chemistry (Weinheim an der Bergstrasse, Germany)no. 15 (2024): e202303373-e202303373
Chemistry (Weinheim an der Bergstrasse, Germany) (2023)
引用0浏览0WOS引用
0
0
Angewandte Chemie (International ed. in English)no. 27 (2023): e202304966-e202304966
Shay P. P. Docherty,Sumanta Banerjee,William Clegg, Fiona J. J. Palin,Alan R. R. Kennedy,Stuart D. D. Robertson,Robert E. E. Mulvey
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIEno. 5 (2023)
CHEMICAL COMMUNICATIONSno. 1 (2023): 91-94
Chemistry – A European Journalno. 55 (2022): e202201085-e202201085
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONSno. 12 (2022): 1217-+
Polar Organometallic Reagentspp.49-95, (2022)
加载更多
作者统计
合作学者
合作机构
D-Core
- 合作者
- 学生
- 导师
数据免责声明
页面数据均来自互联网公开来源、合作出版商和通过AI技术自动分析结果,我们不对页面数据的有效性、准确性、正确性、可靠性、完整性和及时性做出任何承诺和保证。若有疑问,可以通过电子邮件方式联系我们:report@aminer.cn