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Jameson has contributed significantly to a fundamental understanding of the NMR chemical shift as a molecular electronic property. One characteristic of Jameson’s work is her interest in general trends and over-arching relationships, not just specific systems. Her contributions have usually involved providing the basis for a fundamental understanding of a limited body of data, and on this basis, predicting a systematic global pattern which emerges much later. The NMR chemical shift is a difference between two values of the nuclear magnetic shielding. Part of the motivation of Jameson’s work in NMR in the gas phase has been to understand the way in which intermolecular interactions affect the nuclear magnetic shielding, in other words, the exploration of the nuclear magnetic shielding surface, analogous to the intermolecular potential energy surface. In 1993 Jameson’s ab initio calculations showed that in the rare gas pair the shape of the purely theoretical shielding surface is indeed of a shape much like that predicted by Jameson nearly twenty years earlier. Almost all the reported studies of the effects of molecular collisions on the NMR chemical shift in the gas phase have emerged from Jameson’s laboratory. Her work forms the basis for the wide application of Xe NMR shifts for probing various polycrystalline surfaces, zeolites, other porous solids, and polymers.
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Membranesno. 768 (2023): 768-768
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Phytochemistry (2022): 113210-113210
Biomimetic Lipid Membranes: Fundamentals, Applications, and Commercializationpp.109-165, (2019)
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