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Work in our group targets synthetic inorganic chemistry, with the primary goal being to make, purify, and study molecules and materials that are interesting by virtue of their unusual structures and chemical reactivity.
We have extensive experience in the synthesis and study of new and unusual molecular inorganic and organometallic compounds of the d-, p-, and f- block elements. The emphasis is on preparing compounds that exhibit novel reactivity and/or catalytic behavior, particularly in the context of activation of small molecules such as H2, N2, O2, CO2 and N2O. In addition to the dry-box and Schlenk techniques used to prepare and manipulate compounds, we exploit a variety of characterization methods, including multinuclear NMR(link is external), X-ray crystallography(link is external), EPR and electrochemistry.
We have extensive experience in the synthesis and study of new and unusual molecular inorganic and organometallic compounds of the d-, p-, and f- block elements. The emphasis is on preparing compounds that exhibit novel reactivity and/or catalytic behavior, particularly in the context of activation of small molecules such as H2, N2, O2, CO2 and N2O. In addition to the dry-box and Schlenk techniques used to prepare and manipulate compounds, we exploit a variety of characterization methods, including multinuclear NMR(link is external), X-ray crystallography(link is external), EPR and electrochemistry.
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Journal of the American Chemical Societyno. 2 (2024): 1257-1261
Michael A. Boreen, Christopher Z. Ye,Andrew Kerridge,Karl N. McCabe,Brighton A. Skeel,Laurent Maron,John Arnold
INORGANIC CHEMISTRYno. 23 (2022)
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