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At Purdue University, Rothwell established his independent career in chemistry in the area of early transition metal organometallic chemistry. He pioneered the use of bulky aryl oxide ligands as ancillaries in organometallic reaction chemistry and delineated a number of remarkable thermal and photochemical carbon–hydrogen activation processes. He developed and patented niobium and tantalum hydride aryloxide complexes for the hydrogenation of arylphosphines. He also developed a class of aryloxide ligands that were resistant to intramolecular cyclometallation. He is author of over 200 scientific publications and coauthor of the book “Metal Alkoxides” with D. C. Bradley and R. C. Mehrotra. He received several awards for his pioneering chemistry including the Camille and Henry Dreyfus Teacher-Scholar Award, 1986–1988, an Alfred P. Sloan Fellowship, 1987–1989, the Fresenius Award administered by Phi Lambda Upsilon in 1987, the Corday–Morgan Medal and Prize of the Royal Society of Chemistry in 1990, and in 2001, was a Japanese Society for the Promotion of Science Scholar.
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Inorganic Synthesespp.137-140, (2007)
Organometallicsno. 23 (2005): 5759-5766
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