基本信息
浏览量:93
职业迁徙
个人简介
The major activity of my research group is in the area of the elucidation of the mechanisms of organic and organometallic reactions.
We develop and apply modern physical-organic/inorganic methods, including new approaches to classic techniques such as stopped-flow, kinetics, isotopic labelling, and IR/NMR spectroscopy. We have made a number of fundamental contributions to the understanding of the mechanism by which main group reagents (In, B, Si, P etc.) and homogeneous catalysts (Rh, Pd, Cu, Au, H, OH, etc.) function, frequently resulting in the replacement of deep-seated mechanistic or structural dogma with simpler and more coherent explanations. Examples include TMS-diazomethane activation, protodeboronation and solvolysis of organoboron reagents, transboronation, asymmetric induction by chiral ligands, alkene and alkyne metathesis, and stereochemical pathways in metal allyl chemistry, organocatalysis.
In parallel with this work we develop, frequently via academic/industrial collaboration, reactions and processes of utility to the synthetic chemist. Prime examples include gold-catalysed direct arylations, acceleration of amide solvolysis, chiral ligand design, alkene hydroamination and diamination, and Ar-X to Ar-Y type rearrangements.
We develop and apply modern physical-organic/inorganic methods, including new approaches to classic techniques such as stopped-flow, kinetics, isotopic labelling, and IR/NMR spectroscopy. We have made a number of fundamental contributions to the understanding of the mechanism by which main group reagents (In, B, Si, P etc.) and homogeneous catalysts (Rh, Pd, Cu, Au, H, OH, etc.) function, frequently resulting in the replacement of deep-seated mechanistic or structural dogma with simpler and more coherent explanations. Examples include TMS-diazomethane activation, protodeboronation and solvolysis of organoboron reagents, transboronation, asymmetric induction by chiral ligands, alkene and alkyne metathesis, and stereochemical pathways in metal allyl chemistry, organocatalysis.
In parallel with this work we develop, frequently via academic/industrial collaboration, reactions and processes of utility to the synthetic chemist. Prime examples include gold-catalysed direct arylations, acceleration of amide solvolysis, chiral ligand design, alkene hydroamination and diamination, and Ar-X to Ar-Y type rearrangements.
研究兴趣
论文共 394 篇作者统计合作学者相似作者
按年份排序按引用量排序主题筛选期刊级别筛选合作者筛选合作机构筛选
时间
引用量
主题
期刊级别
合作者
合作机构
Roderick P Bunschoten, Frederik Peschke,Andrea Taladriz-Sender, Emma Alexander,Matthew J Andrews,Alan R Kennedy, Neal J Fazakerley,Guy C Lloyd Jones,Allan J B Watson,Glenn A Burley
Journal of the American Chemical Society (2024)
CHEMICAL SCIENCEno. 12 (2024): 4331-4340
Yuan Gao,Andrew M. R. Hall, Nicole A. Fohn,Edward J. King, Lloyd A. L. Mitchell, George A. Steedman,Guy C. Lloyd-Jones
Journal of the American Chemical Societyno. 32 (2023): 18126-18140
引用0浏览0WOS引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
IUPAC Standards Online (2023)
引用0浏览0引用
0
0
加载更多
作者统计
合作学者
合作机构
D-Core
- 合作者
- 学生
- 导师
数据免责声明
页面数据均来自互联网公开来源、合作出版商和通过AI技术自动分析结果,我们不对页面数据的有效性、准确性、正确性、可靠性、完整性和及时性做出任何承诺和保证。若有疑问,可以通过电子邮件方式联系我们:report@aminer.cn